Performance Evaluation of New Advanced Zr Alloys for BWRs and PWRs/VVERs Vol. I

(ZIRAT22/IZNA17)

To meet the current situation with more aggressive reactor environments (higher burnups, changing water chemistries and loading patterns), and resolving fuel performance issues such as BWR channel bowing and PWR assembly bowing, a large number of zirconium alloys have been and are being developed. The main driver for the initial material development in Pressurised Water Reactors (PWRs) has been to reduce corrosion rates and Hydrogen Pick-Up Fractions (HPUFs), which have occasionally limited the maximum discharged burnup.

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Performance Evaluation of New Advanced Zr Alloys for BWRs and PWRs/VVERs Vol. II

(ZIRAT22/IZNA17)

To meet the current situation with more aggressive reactor environments (higher burnups, changing water chemistries and loading patterns), and resolving fuel performance issues such as BWR channel bowing and PWR assembly bowing, a large number of zirconium alloys have been and are being developed. The main driver for the initial material development in Pressurised Water Reactors (PWRs) has been to reduce corrosion rates and Hydrogen Pick-Up Fractions (HPUFs), which have occasionally limited the maximum discharged burnup.

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Key Emerging Issues and Recent Progress related to Structural Materials Degradation (PWRs, VVERs, CANDUs and BWRs)

(LCC12)

During operation, the materials used for the construction of components react with light water reactor environment and cause component degradation, including cracking at welds and piping. Such degradation is due to irradiation, corrosion, fatigue, and other damage mechanisms, and has remained a severe opera­tional challenge for utilities. Details on such degradation are reg­ularly reported and published in scientific journals and at utility workshops and conferences. Foremost in the latter category are those organized since 1983 by NACE, TMS, ANS and CNS in the Environmental Degradation of Water Reactor Materials.

This Report contain highlights from the 17th Inter­national Conference on Environmental Degradation of Materials in Nuclear Power Systems-Water Reactors, which was held in Ottawa, Canada in August 2015. It covers PWRs, VVERs, CANDUs and BWRs. Over 150 papers were published at this conference and this Report cover diverse topics touching on specific degradation modes in various alloys, such as:

  • PWSCC of cold worked Alloy 690 and its weld metals
  • Corrosion fatigue of stainless steels in PWRs and BWRs
  • Fuel cladding materials
  • Cracking of Alloy 718 and X750
  • Flow assisted corrosion
  • Oxide films and characterisation in PWR Secondary systems
  • SCC of Alloy 82 and 182 welds
  • IASCC of stainless steels
  • Irradiation studies involving ion and neutron irradiation
  • Synergistic effects of thermal ageing and neutron embrittlement
  • Alloy 600 oxidation and mechanisms in PWRs
  • PWR Field experience
  • Advances in in-situ monitoring and ex-plant and mockup component evaluation
  • Generation IV materials research
  • Fundamental studies involving new state-of-the-art microscopy and other techniques
  • Fukushima accident related research on SS corrosion in sea water
  • Dry Cask Storage System and Waste Container Corrosion

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Environmentally-Assisted Degradation of Structural Materials in Water Cooled Nuclear Reactors – An Introduction

(SMDR)
This Report is an updated and expanded version of the 2006 ANT International Report entitled: “Environmentally-assisted degradation of structural materials in water cooled nuclear reactors” authored by Dr. Peter Ford.

The objective of this Report are twofold: first, to provide an updated edition of the 2006 Report cited above and, second, to provide a text-book that complement the 4-day webinar on environmentally-assisted degradation of structural materials.

The Report is intended for people new to the subject, or who need a “refresher” on the essential factors behind component failures and the subsequent mitigation actions. Such a focus is critical at this time, given the ongoing retirement of experienced personnel and the loss of “corporate memory” relating to the management of materials degradation. This loss is being felt in areas of reactor license renewal, power uprates, load following, and the certification and construction of advanced designs of both BWRs and PWRs.

In the same series as this updated and expanded Report, there are four other detailed Reports that analyse the behaviour of structural material degradation of various alloys commonly used in Pressurised Water Reactors (PWR/VVER) and Boiling Water Reactors (BWR).

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Key Emerging Issues and Recent Progress Related to Plant Chemistry/Corrosion (PWRs, VVERs, CANDUs, PHWRs, and Auxiliary Systems)

(LCC12)

The 20th Nuclear Plant Chemistry (NPC) International Conference, which started in Bournemouth (UK) and held every other year, was held in Brighton (UK) in October 2016. It is the most im­portant conference related to chemistry in Nuclear Power Plants, and covers many new results in this area. The key information presented at this Conference is covered in two separate LCC12 Reports.

This Report does not only covers PWRs, VVERs, CANDUs, PHWRs and auxiliary systems issues but also summarizes and analyses the results to assess in which specific situation the results are applicable and give the point of view of experts of ANT International that atended the Conference.

The second report covers BWRs and Fukushima response.

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Key Issues in Plant Chemistry and Corrosion in BWRs – 2016

(LCC12)

The 20th Nuclear Plant Chemistry (NPC) International Conference, which started in Bournemouth (UK) and held every other year, was held in Brighton (UK) in October 2016. It is the most im­portant conference related to chemistry in Nuclear Power Plants, and covers many new results in this area. The key information presented at this Conference is covered in two separate LCC12 Reports.

This Report summarizes the BWR related papers from the conference and is designed to provide updated information with the author’s critique and analysis for the benefit of the ANT International/LCC customers. The Report is expected to be a compre­hensive document summarising the latest information on BWR water chemistry that would benefit the BWR operators and regulators.

The second report covers PWRs, VVERs, CANDUs, PHWRs and auxiliary systems issues.

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Covering the Zr Related Results Published During 2015-2016

(ZIRAT21/IZNA16)

The overall objective of the ZIRAT Programme is to enable the
nuclear utilities and laboratories to:

  • Gain increased understanding of material behaviour related to
    successful core options for the back end of the fuel cycle.

The objective is met through review and evaluation of the most recent data on zirconium alloys, identification of the most important new information, and discussion of its significance in relation to fuel performance now and in the future. Included in the review are topics on materials research and development, fabrication, component design and in-reactor performance.

The evaluations are based on the large amount of non-proprietary data presented at technical meetings, published in the literature and provided through discussions with zirconium materials manufacturers.

The open literature information will be collected throughout the year and the data most important to the utilities and laboratories is selected for the Annual Report. The large collective experience gained by the reviewers in past and current projects is an important factor in making the evaluation, hence ensuring that the presented compiled information is put in perspective, and that the most important information is emphasized. The data will be useful to
utilities and laboratories to assist them in evaluating:

  • New and potential fuel performance problems and performance limits
  • The effect of new data on current fuel design bases
  • Qualifications desirable for new design features
  • The effect of modified or new fabrication processes on properties
  • Potential use of new Quality Control (QC) methods
  • QC requirements for new materials features
  • Qualification needs for new alloys
  • Lessons learned from fuel performance regarding design bases, fabrication process control, QC and reactor operation

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Hot Cell Post-Irradiation Examinations Volume II

(ZIRAT21/IZNA16)

Maintaining and improving reliability of fuel and structural components requires an understanding of their behaviour in reactor and the mechanisms that have been observed to cause failures. A key factor in improving reliability is the identification of the cause or causes of failure. Such information, in turn, requires the examination and analysis of irradiated fuel (including bundle hardware) and structural components at reactor sites (poolside examinations), in hot cells and in related laboratories. Thus, to make progress toward ultra-high reliability fuel and to reduce the potential for fuel failure, it is imperative to examine both failed and non-failed (reference) fuel.

Post-irradiation examinations (PIE) provide fuel vendors and nuclear utilities with data on how newly developed or established materials withstand normal operating conditions in new environments. Post-irradiation examinations are largely carried out at a Hot Cell Laboratory where irradiated fuel rods and other hardware can be received, handled, examined, and tested. The investigation results provide information for fuel and component improvement and, thereby, can potentially enhance operating efficiency and reliability.

  • Section 1 provide an overview about the status of post-irradiation examination (PIE) and inspection techniques for nuclear fuel and other zirconium alloy components used in CANDU reactors and their applications for analysis of materials behaviour in a CANDU reactor core.
  • Section 2 discusses these techniques along with real world examples of in-reactor microstructural changes and impact on material behaviour.
  • Section 3 provides information on PIE capabilities of some of the major hot cell facilities. This information will be useful for utility engineers when they need to have PIE performed on failed nuclear fuel or other components.

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Nuclear Fuel Behaviour Under RIA Conditions

(ZIRAT21/IZNA16)

The design basis RIA in a PWR is the Control Rod Ejection (CRE), while in a BWR, it is the Control Rod Drop Accident (CRDA). The CRE is based on the assumption of a mechanical failure of the control rod drive mechanism located on the reactor vessel top, followed by the ejection of the mechanism and the control rod by the internal reactor pressure. The resulting, significant power surge is limited partly by Doppler feedback and finally terminated by the reactor trip. The BWR CRDA is assumed to occur if a control rod is detached from its drive mechanism in the core bottom, stays stuck while inserted in the core, then if loosened, drops out of the core by gravity, without involvement of a change in reactor pressure as in the CRE. Partly as a result of these differences, the BWR power pulses are slower than for a PWR. The pulse widths for PWRs are in the range of 10–30 ms and for BWRs in the range of 20–60 ms.
The reactivity transient during an RIA results in a rapid increase in fuel rod power leading to a nearly adiabatic heating of the fuel pellets.
The RIA-simulation experiments conducted in the 1960’s and 1970’s using zero or low burnup test rods showed that cladding failure occurred primarily by either:

  • Post-Departure from Nucleate Boiling (DNB)
  • Cladding contact with molten fuel

This Special Topic Report (STR) will give insight and understanding of the parameters impacting the fuel RIA performance and reviews the applicability of the data to high burnup fuel cladding. The STR also provides the latest RIA regulatory acceptance criteria.

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LCC1 Annual Report

The Report covers the following topics:

  • Coolant Quality and Control Issues – PWR Water Chemistry – BWR water chemistry
  • Materials selection for the primary BWR and PWR circuits
  • Primary Circuit Corrosion (BWRs and PWRs) – SCC, PWSCC in PWRs – SCC in BWRs and remedies (HWC, NMCA)
  • Dose Rate Buildup and Control
  • Fuel/Water Chemistry Interaction

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